Rydberg state ionization by half-cycle-pulse excitation: strong kicks create slow electrons

The asymptotic velocity distribution of electrons ionized in half-cycle-pulse excitation of high Rydberg states (n = 34), placed in a static electric field, is studied using electron velocity-map imaging. At weak half-cycle pulse strengths, the electrons escape over the saddle point in the potential. For strong half-cycle pulses, the electrons are emitted in the direction of the field kick. The much slower and less intense half cycle of opposite polarity, which necessarily follows the main half-cycle pulse, strongly affects the momentum distribution and reduces the excess energy of the electrons significantly.