We analyze the finite-size corrections to the free energy of crystals with a fixed center of mass. When we explicitly correct for the leading (ln N/N) corrections, the remaining free energy is found to depend linearly on 1/N. Extrapolating to the thermodynamic limit (N®oo), we estimate the free energy of a defect-free crystal of particles interacting through an r-12 potential. We also estimate the free energy of perfect hard-sphere crystal near coexistence: at rs3 = 1.0409, the excess free energy of a defect-free hard-sphere crystal is 5.918 89(4)kT per particle. This, however, is not the free energy of an equilibrium hard-sphere crystal. The presence of a finite concentration of vacancies results in a reduction of the free energy that is some two orders of magnitude larger than the present error estimate.

J. Chem. Phys.

Polson, J. M., Trizac, E., Pronk, S., & Frenkel, D. (2000). Finite-size corrections to the free energies of crystalline solids. J. Chem. Phys., 112, 5339–5342. doi:10.1063/1.481102