Evidence for entropy-driven demixing in hard-core fluids
We report the first observation, by computer simulation, of a purely entropic demixing transition in a three-dimensional binary hard-core mixture. This transition is observed in a mixture of large and small cubes. We also find evidence for demixing in other hard-core fluids and, in the case of an athermal polymer solution, we observe a purely entropy-driven polymer collapse. For the study of both the hard-core demixing and polymer collapse, it was essential to use novel collective Monte Carlo moves.
|Journal||Phys. Rev. Lett.|
Dijkstra, M, & Frenkel, D. (1994). Evidence for entropy-driven demixing in hard-core fluids. Phys.Rev.Lett., 72, 298–300.