Anomalous temperature dependence of vibrational lifetimes in water and ice

Woutersen, Sander; Emmerichs, U.; Nienhuys, H.-K.; Bakker, Huib

S. Woutersen (Sander), U. Emmerichs, H.-K. Nienhuys and H.J. Bakker (Huib)

1998

Anomalous temperature dependence of vibrational lifetimes in water and ice

Phys. Rev. Lett. , Volume 81 p. 1106- 1109

We have used femtosecond two-color midinfrared spectroscopy to determine the temperature dependence of the OH-stretching lifetime in dilute HDO:D₂O solution, both in the liquid and solid (ice Ih) state. Like many other properties of water, the vibrational lifetime shows a remarkable temperature dependence: In liquid water the vibrational relaxation of the OH-stretching mode is twice as slow as in ice, and becomes even slower with increasing temperature.

Additional Metadata
Journal	Phys. Rev. Lett.
Organisation	Ultrafast Spectroscopy
Citation APA Style AAA Style APA Style Cell Style Chicago Style Harvard Style IEEE Style MLA Style Nature Style Vancouver Style American-Institute-of-Physics Style Council-of-Science-Editors Style BibTex Format Endnote Format RIS Format CSL Format DOIs only Format	Woutersen, S., Emmerichs, U., Nienhuys, H.-K., & Bakker, H. (1998). Anomalous temperature dependence of vibrational lifetimes in water and ice. Phys.Rev.Lett., 81, 1106–1109.

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