Colloidal particle coordinates in three dimensions can be obtained in 3D samples with a combination of the increased resolution and optical sectioning capabilities of confocal microscopy and fluorescently labeled model core-shell silica colloids. In this work we show how this capability can be used to analyze structure formation in electrorheological fluids on a quantitative basis. We find body-centered-tetragonal (BCT) crystals for colloidal particles in an electric field. Metastable sheet like structures were identified as an intermediate phase prior to BCT crystal formation. Due to finite-size effects induced by the electrode surface the sheets are not randomly oriented, but grow preferentially with a 60degrees tilt with respect to the electric field. Preliminary measurements indicate that flow-aligned sheets form under shear. Finally, we show that in the case that the ionic strength is very low, electric-field-induced dipolar interactions can be present in addition to long-range repulsions between the colloids leading to interesting metastable and equilibrium structures with possibilities for applications in photonic bandgap crystals as well as in model ER studies.

Additional Metadata
Journal Int. J. Mod. Phys. B
Citation
Yethiraj, A, & van Blaaderen, A. (2002). Monodisperse colloidal suspensions of silica and pmma spheres as model electrorheological fluids: A real-space study of structure formation. Int. J. Mod. Phys. B, 16, 2328–2333.